A Fe K-edge XAS study of amethyst     

Francesco Di Benedetto  Francesco D’Acapito  Gabriele Fornaciai  Massimo Innocenti  Giordano Montegrossi  Luca A. Pardi  Silvia Tesi  Maurizio Romanelli 《Physics and Chemistry of Minerals》2010,37(5):283-289

An X-ray absorption spectroscopy (XAS) study of the Fe local environment in natural amethyst (a variety of α-quartz, SiO₂) has been carried out. Room temperature measurements were performed at the Fe K-edge (7,112 eV), at both the X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) regions. Experimental results were then compared with DFT calculations. XANES experimental spectra suggest Fe to occur mainly in the trivalent state, although a fraction of Fe²⁺ is identified. EXAFS spectra, on the other hand, reveal an unusual short distance for the first coordination shell:  = 1.78(2) Å, the coordination number being 2.7(5). These results allow to establish that Fe replaces Si in its tetrahedral site, and that numerous local distortions are occurring as a consequence of the presence of Fe³⁺ variably compensated by protons and/or alkaline ions, or uncompensated. The formal valence of Fe, on the basis of both experimental and DFT structural features, can be either 4+ or 3+. Taking into account the XANES evidences, we suggest that Fe mainly occurs in the trivalent state, compensated by protons, and that a minor fraction of Fe⁴⁺ is stabilised by the favourable local structural arrangement.  相似文献   

ESEEM of industrial quartz powders: insights into crystal chemistry of Al defects     

Maurizio?Romanelli  Francesco?Di BenedettoEmail author  Laura?Bartali  Massimo?Innocenti  Gabriele?Fornaciai  Giordano?Montegrossi  Luca?A.?Pardi  Alfonso?Zoleo  Fabio?Capacci 《Physics and Chemistry of Minerals》2012,39(6):479-490

A set of raw industrial materials, that is, pure quartz and quartz-rich mixtures, were investigated through electron paramagnetic resonance and electron spin echo-envelope modulation spectroscopies, with the aim of evaluating the effective role played by defect centres and of assessing whether they can be used to monitor changes in the physical properties of quartz powders with reference to their health effects. The obtained results point to two interactions of the Al defect centres with H⁺, hosted in sites within the channels parallel and perpendicular to the c axis of quartz, respectively. These two Al/H⁺ (h_Al) centres exhibit a weak chemical bond, and their relative amounts appear to be modified/controlled by the thermo-mechanical processes underwent by powders. Indeed, a mechanically promoted inter-conversion between the two kinds of site is suggested. As a consequence, the h_Al centres are effective in monitoring even modest activations of powders, through thermal or mechanical processes, and they are also supposed to play a specific, relevant role in quartz reactivity during the considered industrial processes.  相似文献   

Numerical modelling of installation effects for diaphragm walls in sand     

Riccardo Conti  Luca de Sanctis  Giulia M. B. Viggiani 《Acta Geotechnica》2012,7(3):219-237

The scopes of this work are to study the mechanisms of load transfer and the deformations of the ground during slurry trenching and concreting in dry sand and to evaluate their effects on service structural loads, wall deflections and ground displacements behind the wall caused by subsequent excavation. A series of three-dimensional finite element analyses was carried out modelling the installation of diaphragm walls consisting of panels of different length. The soil was modelled as either linearly elastic-perfectly plastic or incrementally non-linear (hypoplastic) with elastic strain range. Plane strain analyses of diaphragm walls of identical cross section were also carried out in which wall installation was either modelled or the wall was wished in place (WIP). The analyses predict ground movements consistent with the experimental observations both in magnitude and trend. The results also show that the maximum horizontal wall deflections and structural loads reduce with increasing panel aspect ratio towards a minimum which is about twice the value computed for WIP analyses. Panel aspect ratios should be larger than about three to take advantage of the three-dimensional effects. The pattern and magnitude of surface vertical displacements obtained from linearly elastic-perfectly plastic analyses, no matter whether three- or two-dimensional, are unrealistic.  相似文献   

‘Corrigendum to “Uniform and graded bed-load sediment transport in a degrading channel with non-equilibrium conditions” [International Journal of Sediment Research 35 (2020) 115–124/04-258]’     

Khabat Khosravi  Amir H.N. Chegini  James R. Cooper  Prasad Daggupati  Andrew Binns  Luca Mao 《国际泥沙研究》2021,36(1):163

  相似文献   

Changes in cetacean presence,relative abundance and distribution over 20 years along a trans‐regional fixed line transect in the Central Tyrrhenian Sea     

Antonella Arcangeli  Luca Marini  Roberto Crosti 《Marine Ecology》2013,34(1):112-121

From 1989 to 1992, systematic cetacean surveys were carried out twice weekly along a trans‐regional fixed transect in the Central Tyrrhenian Sea, utilising passenger ferries as research platforms. Using the same protocol and supervised by the same investigators, the research restarted in 2007, providing the opportunity to compare consistent data over a long 20‐year period. The monitored transect (Civitavecchia‐Golfo Aranci) runs along a strategic area just outside the southeastern border of the Pelagos Sanctuary. Over the last two decades, an increasing trend of temperature and salinity, in the deep and intermediate layers, has been documented in the region, as well as general changes over the Mediterranean basin. These changes, together with the increasing impact of some pressures (e.g. maritime traffic) may have led to changes in oceanographic and anthropogenic features and, subsequently, in cetacean presence and distribution. The research aimed to verify whether any changes occurred in the pattern of cetacean occurrence over the 20‐year period along the representative transect in the Central Tyrrhenian Sea. Data from 90 summer weekly runs undertaken in the 1990s were compared with data obtained from 95 runs undertaken in the 2000s. Each ferry run was considered an independent statistical unit: the encounter rate (ER = number of sightings per hour spent on effort) was calculated to compare relative abundance between periods, years and months. Spatial analysis was performed on geographical data using Kernel analysis to map the distribution of sightings. Logistic regression (GLM) was performed to compare habitat preference. Total encounter rate in the 1990s (ER = 0.59 ± CI 0.08) was significantly lower (P < 0.01) compared with the 2000s (ER = 0.94 ± CI 0.15). The same seven out of eight species known for their regular presence in the Mediterranean Sea were sighted in both the investigated periods. The most common species were striped dolphin (Stenella coeruleoalba), fin whale (Balaenoptera physalus) and common bottlenose dolphin (Tursiops truncatus). Neither the pilot whale nor any other rare or occasional species were sighted during the 6 years of the study. Despite the time span, no dramatic changes were observed for any species, bar fin whale, in terms of distribution, relative abundance, group size or habitat preference. Sightings of fin whale have surprisingly increased (+300%, P< 0.001), and their spatial and temporal distribution and habitat preference showed a radical difference between the two periods. The 2000s surveys confirmed the existence of high density areas of cetaceans, especially of fin whale, and the consequent necessity of specific legislative acts for cetacean conservation.  相似文献   

Direct Conversion of Food Waste into 3D Porous Carbon Traps for Selective Adsorption of Cationic Dyes     

Anitha Senthamizhan  Brabu Balusamy  Doriana Debellis  Jose Alejandro Heredia-Guerrero  Giorgio Mancini  Riccardo Carzino  Luca Ceseracciu  Athanassia Athanassiou  Despina Fragouli 《洁净——土壤、空气、水》2023,51(1):2200284

Conversion of waste biomass into valuable functional materials accomplishes the concept of circular economy in the development of sustainable waste management, and also recovery of such resources possibly reduces the requirement of feedstocks. In this scenario, the development of methodologies toward the direct conversion of the raw biomass into solid adsorbent materials without the use of any templates is highly desirable, but exceptionally challenging due to the complexity of the process. Here the direct synthesis of 3D porous carbon traps by a simple, cost-effective, and template-free process starting from a kitchen-based recipe and fermented food waste is described. Precisely, a robust carbon trap is formed with a spongy structure and highly interconnected hierarchical pores after the pyrolysis of a rice-based foam in the air. The developed materials float on water and interact efficiently with cationic dyes at static conditions. Importantly, such performance of the 3D carbon traps is not affected in the presence of anionic dyes, indicating the excellent selectivity towards the adsorption of cationic dyes. The adsorbent can be easily recovered and reused for up to 3 cycles without releasing any byproducts, thus, without causing hazardous risk of any secondary pollution to the environment.  相似文献   

Near-bankfull floods in an Alpine stream: Effects on the sediment mobility and bedload magnitude   总被引：1，自引：0，他引：1  

Riccardo Rainato  Luca Mao  Lorenzo Picco 《国际泥沙研究》2018,33(1):27-34

In a mountain environment, the transport of coarse material is a key factor for many fields such as geomorphology, ecology, hazard assessment, and reservoir management. Despite this, there have been only a few field investigations of bedload, in particular using multiple monitoring methods. In this sense, attention has frequently focused on the effects of “high magnitude/low frequency floods” rather than on “ordinary events”. This study aims to analyze the sediment dynamics triggered by three high-frequency floods (recurrence interval “RI” between 1.1 and 1.7 yr) that occurred in the Rio Cordon basin during 2014. The flood events were investigated in terms of both sediment mobility and bedload magnitude. The Rio Cordon is an Alpine basin located in northeastern Italy. The catchment has a surface area of 5 km², ranging between 1763 and 2763 m above sea level. The Rio Cordon flows on an armored streambed layer, with a stable step-pool configuration and large boulders. Since 1986, the basin has been equipped with a permanent station to continuously monitor water discharge and sediment flux. To investigate sediment mobility, 250 PIT-tags were installed in the streambed in 2012. The 2014 floods showed a clear difference in terms of tracer displacement. The near-bankfull events showed equal mobility conditions, with mean travel distance one order of magnitude higher than the below-bankfull event. Furthermore, only the near-bankfull events transported coarse material to the monitoring station. Both events had a peak discharge up to 2.06 m³ s^-1, but the bedload transport rates differed by more than one order of magnitude, proving that under the current supply-limited condition, the bedload appears more related to the sediment supply than to the magnitude of the hydrological features. In this sense, the results demonstrated that near-bankfull events can mobilize large amounts of material for long distances, and that floods of apparently similar magnitude may lead to different sediment dynamics, depending on the type and amount of sediment supply.  相似文献   

Seismic design of floor–wall joints of multi-storey CLT buildings to comply with regularity in elevation     

Davide Trutalli  Luca Pozza 《Bulletin of Earthquake Engineering》2018,16(1):183-201

The effects of irregularity in elevation of cross-laminated timber buildings have not been fully analysed in literature to provide useful information for the design. In this work, a number of building configurations, regular or irregular in elevation, characterized by a different arrangement per storey of the floor–wall joints have been analysed by means of non-linear dynamic analyses. Comparative results in terms of ratio between the behaviour q-factor of the investigated irregular configurations and that of reference regular ones, show that less dissipative capacity can be expected if the building is irregular due to a disequilibrium among storeys between the actual and the required strength provided by the floor–wall joints. A correlation method to estimate the behaviour q-factor for perfectly regular cross-laminated timber buildings is here presented and extended to in-elevation irregular ones. A new empirical formulation to assess the reliable corrective factor accounting for the irregularity in elevation of cross-laminated timber buildings, according to Eurocode 8 provisions, is also proposed. A final discussion about the implications of in-elevation irregularity on the building design is reported.  相似文献   

Micro-seismic monitoring after the shipwreck of the Costa Concordia at Giglio Island (Italy)     

Andrea Fiaschi  Luca Matassoni  Alessia Lotti  Gilberto Saccorotti 《Acta Geophysica》2017,65(5):1019-1027

A micro-seismic network was used for monitoring the wreck of the Costa Concordia cruise ship, wrecked and run agrounded along the Giglio Island coasts during the night of 13 January 2012, until its removal. The seismic traces were processed by means of real-time and “a posteriori” procedures to detect transients that could be ascribed to wreck movements on the sea bed to integrate this information in an early warning system for assessing the wreck stability. After a first discrimination of the transients using amplitude criteria we proceeded to the localization of the detected signals to focus the attention only on the transients originated in the shipwreck resting area. The results showed that most of the events localized on the wreck were likely related to human work activities or sudden internal brittle failure but not to displacements on the seafloor. Instead, the displacements are associated to the impact on the vessel of great sea storms which approach were well correlated with the increasing seismic noise at low frequency. The carried out procedures based on this unique dataset represent an opportunity to test seismic monitoring techniques also in not usual engineering context to support emergency management activities.  相似文献   

The Intra-Pontide ophiolites in Northern Turkey revisited:From birth to death of a Neotethyan oceanic domain     

Michele Marroni  M.Cemal Goncüoglu  Chiara Frassi  Kaan Sayit  Luca Pandolfi  Alessandro Ellero  Giuseppe Ottria 《地学前缘(英文版)》2020,11(1):129-149

The Anatolian peninsula is a key location to study the central portion of the Neotethys Ocean(s)and to understand how its western and eastern branches were connected.One of the lesser known branches of the Mesozoic ocean(s)is preserved in the northern ophiolite suture zone exposed in Turkey,namely,the Intra-Pontide suture zone.It is located between the Sakarya terrane and the Eurasian margin(i.e.,Istanbul-Zonguldak terrane)and consists of several metamorphic and non-metamorphic units containing ophiolites produced in supra-subduction settings from the Late Triassic to the Early Cretaceous.Ophiolites preserved in the metamorphic units recorded pervasive deformations and peak metamorphic conditions ranging from blueschist to eclogite facies.In the nonmetamorphic units,the complete oceanic crust sequence is preserved in tectonic units or as olistoliths in sedimentary melanges.Geochemical,structural,metamorphic and geochronological investigations performed on ophiolite-bearing units allowed the formulation of a new geodynamic model of the entire"life"of the IntraPontide oceanic basin(s).The reconstruction starts with the opening of the Intra-Pontide oceanic basins during the Late Triassic between the Sakarya and Istanbul-Zonguldak continental microplates and ends with its closure caused by two different subductions events that occurred during the upper Early Jurassic and Middle Jurassic.The continental collision between the Sakarya continental microplate and the Eurasian margin developed from the upper Early Cretaceous to the Palaeocene.The presented reconstruction is an alternative model to explain the complex and articulate geodynamic evolution that characterizes the southern margin of Eurasia during the Mesozoic era.  相似文献